3. Man United 3-2 Liverpool (September 19, 2010)
Dimitar Berbatov may not have always put in 100 per cent effort during his time in Manchester but his brilliant hat-trick in this early season fixture forever wrote him into United folklore. Steven Gerrard managed to haul Liverpool back into the game with two goals but the Bulgarian’s header to complete his treble on 84 minutes sealed a late win for the Red Devils.